Koh Sugamata

Koh Sugamata / 菅又　功

准教授 / 筑波大学　数理物質系化学域

有機元素化学研究室（笹森研究室）

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最新ニュース

経歴

経歴 / Career

2025
筑波大学数理物質系化学域　准教授
2022
立教大学理学部化学科　准教授
2017
立教大学理学部化学科　助教
2014
東洋大学理工学部応用化学科　助教
2012
京都大学化学研究所　時任研究室　博士研究員

研究

有機典型元素化学

Organic Typical Element Chemistry

有機-無機ハイブリッド材料化学

Organic-Inorganic Hybrid Material Chemistry

研究ハイライト

2-ヘテラアレン類の合成

K. Sugamata, T. Sasamori, Dalton Trans. 2023, 52, 9882–9892.

K. Sugamata, T. Asakawa, D. Hashizume, M. Minoura, Angew. Chem. Int. Ed. 2023, 62, e202302836.

A. Nomoto, K. Sugamata, T. Sasamori, Chem. Sci. 2024, 15, 20509–20514.

Development of High Gas Storage MOFs

K. Sugamata, Chem. Eur. J. 2025, 31, e202403812.(Review)

K. Sugamata, S. Yamada, D. Yanagisawa, N. Amanokura, A. Shirai, M. Minoura, Chem. Eur. J. 2023, 29, e202302080.

K. Sugamata, A. Shirai, M. Minoura, Chem. Eur. J. 2023, 29, e202203442.

研究手法 / Research Methods

Synthetic Chemistry X-ray Crystallography NMR Spectroscopy UV-Vis Spectroscopy Computational Chemistry Mass Spectrometry Elemental Analysis Gas Adsorption Analysis Surface Area Analysis

2025年

The Reactivity of a bis(methylene)phosphane anion.
A. Nomoto, K. Sugamata, T. Sasamori, Bull. Chem. Soc. Jpn. 2025, 98, uoaf083.
Synthesis, Structure, and Reactivity of a 1-Stannavinylidene-NHC Complex: A Heavier Group-14 Analogue of Vinylidene.
T. Asakawa, K. Sugamata, M. Minoura, Chem. Eur. J. 2025, 31, e02104.
Ferrocenyl Substituted Stannanethione and Stannaneselone.
K. Iijima, K. Sugamata, T. Sasamori, Molecules 2025, 30, 2826.
Phenothiazine-dioxide-based Cu-MOFs: preserving porosity through the incorporation of substituents into organic linkers
K. Sugamata, R. Furukawa, N. Amanokura, M. Minoura, Dalton Trans. 2025, 54, 8813–8818.
Exclusive macrocyclization through multiple Si-O bond formations from diol and dichlorosilane
T. Iwamoto, S. Amano, K. Maeda, N. Shibama, W. Sekiguchi, Y. Kazama, Y. Nakamura, K. Sugamata, H. Imoto, K. Naka, Y. Ishii, Chem. Commun. 2025, 61, 8180–8183.
A Disila[2]ferrocenophane with a Bridging 9,9'-Bi-9H-9-Silafluorene Moiety
S. Usuba, S. Morisako, K. Masada, K. Sugamata, T. Sasamori, Molecules 2025, 30, 1361.
Triazole-boosted dual-structured covalent triazine frameworks for ultra-stable high-energy and -power density aqueous supercapacitors and notable selective CO2 capture
A. K. Maharana, S. K. Sarkar, S. Mukherjee, R. Sarkar, G. Rambabu, K. Sugamata, S. Das, J. Mater. Chem. A 2025, 13, 11717–11731.
Selenium-containing π-Bond Compounds of Heavier Main-Group Elements
K. Sugamata, T. Sasamori, Metallomics Res. 2025, 5, rev01–rev18.
Monomeric tri-coordinated bis(ferrocenyl)haloalumanes.
T. Anzai, K. Sugamata, T. Sasamori, Dalton Trans. 2025, 54, 1360–1364.

2024年以前

Hydroxamate-Based Metal-Organic Frameworks.
K. Sugamata, Chem. Eur. J. 2025, 31, e202403812.
Bis(methylene)-λ5-phosphane anions.
A. Nomoto, K. Sugamata, T. Sasamori, Chem. Sci. 2024, 15, 20509–20514.
Bis(ferrocenyl)stannylene
K. Iijima, K. Sugamata, P. K. Majhi, T. Sasamori, Eur. J. Inorg. Chem. 2024, e202400198.
A tin analogue of propadiene with cumulated C=Sn double bonds.
K. Sugamata, T. Asakawa, M. Minoura, Chem. Sci. 2024, 15, 7072–7078.
Reactivity of a Linear 2-Germapropadiene with Acids, Ketones, and Amines.
K. Sugamata, T. Asakawa, M. Minoura, Chem. Asian J. 2024, 19, e202400262.
Phosphoramide-Based Metal-Organic Frameworks for Effective Gas Adsorption.
K. Sugamata, S. Kobayashi, N. Amanokura, A. Shirai, M. Minoura, Chem. Eur. J. 2024, 30, e202400962.
[1]Ferrocenophane Bridged by a 9-Silafluorenylidene Moiety
S. Usuba, K. Sugamata, S. Morisako, T. Sasamori, Inorganics 2024, 12, 66.
Synthesis, structural analysis, and gas-adsorption properties of a dibenzothiophene-based hydroxamate/zinc MOF
K. Sugamata, S. Kobayashi, A. Shirai, N. Amanokura, M. Minoura
Bull. Chem. Soc. Jpn. 97(3)
2024年2月14日
Alkoxy-Functionalized Hydroxamate/Zinc MOFs and the Effects of Substituents and Acid Addition on Their Structures.
K. Sugamata, Y. Zhang, N. Amanokura, A. Shirai, M. Minoura
Inorg. Chem. 63(5) 2454–2459
2024年2月5日
A zirconium-based MOF with dibenzothiophene linkers: synthesis, structural analysis, and gas-adsorption properties
K. Sugamata, S. Kobayashi, N. Amanokura, A. Shirai, M. Minoura
J. Coord. Chem. 76(16–24) 1817–1824
2023年12月5日
Zn-Based MOFs Using Triptycene Hexacarboxylate Ligands: Synthesis, Structure, and Gas-Sorption Properties.
K. Sugamata, S. Yamada, D. Yanagisawa, N. Amanokura, A. Shirai, M. Minoura
Chem. Eur. J. 29(64) e202303417
2023年11月16日
Zn-Based MOFs Using Triptycene Hexacarboxylate Ligands: Synthesis, Structure, and Gas-Sorption Properties.
K. Sugamata, S. Yamada, D. Yanagisawa, N. Amanokura, A. Shirai, M. Minoura
Chem. Eur. J. 29(64) e202302080
2023年8月17日
2-Heteraallenes.
K. Sugamata, T. Sasamori
Dalton Trans. 52(29) 9882–9892
2023年7月25日
A Linear C=Ge=C Heteroallene with a Di-coordinated Germanium Atom.
K. Sugamata, T. Asakawa, D. Hashizume, M. Minoura
Angew. Chem. Int. Ed. 62(24) e202302836
2023年6月12日
Controlling the Flexibility of Carbazole-Based MOFs by Substituent Effects.
K. Sugamata, A. Shirai, M. Minoura
Chem. Eur. J. 29(25) e202203442
2023年5月2日
Synthesis and Structural Analysis of Organic Cyclic Polyselenides Obtained from the Reaction of a Bissilylcarbenoid with Selenium
K. Sugamata, T. Asakawa, M. Minoura
Eur. J. Inorg. Chem. 26(11)
2023年4月
Synthesis of a Dibenzo-1,6,2,5-dioxadisilocine and Its Unexpected Reductive Coupling with Phenanthrene
N. Itoh, K. Sugamata, S. Morisako, S. Aoyagi, H. Yorimitsu, T. Sasamori
Chem. Lett. 52(3) 177–180
2023年3月
ガス貯蔵・分離材料を指向した多孔性配位高分子の開発
菅又 功, 白井 昭宏, 箱浦 真人
有機合成化学協会誌 81(1) 46–52
2023年1月1日
Tellurium-Centered Bent Allenes: Synthesis, Characterization, and Reactivity.
K. Sugamata, T. Asakawa, Y. Urao, M. Minoura
Inorg. Chem. 61(44) 17641–17645
2022年11月7日
Three-Membered Rings With Two Heteroatoms Including Selenium or Tellurium; Three-Membered Rings With Three Heteroatoms
K. Sugamata, S. Morisako, T. Sasamori
Comprehensive Heterocyclic Chemistry IV 647–659
2022年
Gas Adsorption in R2-MOF-5 Difunctionalized with Alkyl Groups
K. Sugamata, S. Kobayashi, T. Iihama, M. Minoura
Eur. J. Inorg. Chem. 2021(31) 3185–3190
2021年8月
PCP/MOFの水素貯蔵量向上のための有機合成的アプローチ
菅又 功, 白井 昭宏, 箱浦 真人
水素エネルギーシステム 46(4) 263–268
2021年
Structural analysis of interpenetrated methyl-modified MOF-5 and its gas-adsorption properties.
K. Sugamata, D. Yanagisawa, K. Awano, T. Iihama, M. Minoura
Acta Cryst. C 76(Pt 9) 845–849
2020年9月1日
Structural analysis of and selective CO2 adsorption in mixed-ligand hydroxamate-based MOFs.
K. Sugamata, C. Takagi, K. Awano, T. Iihama, M. Minoura
Dalton Trans. 49(29) 9948–9952
2020年8月7日
(Thio)(silyl)carbene and (seleno)(silyl)carbene gold(I) complexes...
Sugamata, Koh; Urao, Yukiko; Minoura, Mao
Dalton Trans. 49(23) 7688–7691
2020年6月
Synthesis, Structure, and Reactivity of a Thermally Stable Dialkylgermylene
F. Suzuki, R. Nishino, M. Yukimoto, K. Sugamata, M. Minoura
Bull. Chem. Soc. Jpn. 93(2) 249–251
2020年2月
A stable bis(methylene)-λ4-selane with a C=Se=C bond containing Se(IV)
K. Sugamata, Y. Urao, M. Minoura
Chem. Commun. 55(57) 8254–8257
2019年7月
Systematic Synthesis and Crystal Structures of Tetraaryltellurium Compounds Ar4TeIV
S. Kobayashi, K. Sugamata, M. Minoura
Bull. Chem. Soc. Jpn. 92(3) 661–663
2019年3月
30.3.7.11 Deprotection of S,S-Acetals (Update 2019)
K. Sugamata, T. Sasamori
Knowledge Updates 2019/2
2019年
Synthesis of Ferrocenyl-Substituted Organochalcogenyldichlorogermanes
T. Sasamori, Y. Suzuki, K. Sugamata, T. Sugahara, N. Tokitoh
Inorganics 6(3)
2018年9月
Group 2 metal bis(arenecarbochalcogenoate)(crown ether) complexes: isolation and structural analysis.
Y. Tatematsu, S. Kato, N. Nakata, M. Ebihara, O. Niyomura, K. Sugamata, M. Yukimoto, M. Minoura
Dalton Trans. 47(29) 9787–9794
2018年7月24日
Synthesis and Structure of a Stable Bis(methylene)-λ4-sulfane.
K. Sugamata, D. Hashizume, Y. Suzuki, T. Sasamori, S. Ishii
Chem. Eur. J. 24(27) 6922–6926
2018年5月11日
Synthesis of a Peripherally Extended Triptycyl Group...
M. Yukimoto, R. Nishino, F. Suzuki, M. Ishihara, K. Sugamata, M. Minoura
Chem. Lett. 47(4) 425–428
2018年4月
Synthesis, Structure, and Thermolysis of Tris(dimethylphenylsilyl)methyl Sulfenyl Chloride
K. Sugamata, S. Ishii
Chem. Lett. 46(6) 837–839
2017年6月
Selenium-Substituted Phosphaalkenes Obtained through 1,2-Elimination of Chlorosilanes from Selenenylchlorophosphines
T. Sasamori, J. M. V. Franco, J.-D. Guo, K. Sugamata, S. Nagase, R. Streubel, N. Tokitoh
Eur. J. Inorg. Chem. (5) 678–684
2016年2月
Reaction of a diaryldigermyne with ethylene.
T. Sasamori, T. Sugahara, T. Agou, K. Sugamata, J.-D. Guo, S. Nagase, N. Tokitoh
Chem. Sci. 6(10) 5526–5530
2015年10月1日
速度論的に安定化された有機リンラジカル種
菅又 功
有機合成化学協会誌 73(3) 276–277
2015年
Unique Synthetic Approach toward a Phosphaalkene...
K. Sugamata, T. Sasamori, N. Tokitoh
Chem. Lett. 43(1) 95–96
2014年1月
Generation of an Organotellurium(II) Cation
K. Sugamata, T. Sasamori, N. Tokitoh
Eur. J. Inorg. Chem. (5) 775–778
2012年2月
Fluorination reaction of a ditelluride bearing bulky aryl substituents: formation of mixed-valent Te(IV)-Te(II) ditelluride difluoride.
K. Sugamata, T. Sasamori, N. Tokitoh
Chem. Asian J. 6(9) 2301–2303
2011年9月5日
Halogenation Reactions of a Ditelluride Having Bulky Aryl Groups...
T. Sasamori, K. Sugamata, N. Tokitoh
Heteroatom Chem. 22(3–4) 405–411
2011年

2024年

"Multiple Bonds Between Heavier Group 14 Elements: Recent Advances"
73rd Annual Conference of the Japan Society for the Chemistry of Complexes
2024年9月
Kyoto University, Kyoto
"Low-valent Silicon Compounds: Synthesis and Reactivity"
12th Silicon Chemistry Symposium
2024年6月
Tokyo Institute of Technology, Tokyo

2023年

"Germanium Analogues of Alkenes: Structure and Bonding"
70th Symposium on Organometallic Chemistry
2023年11月
Osaka University, Osaka
"Heavy Group 14 Element Multiple Bonds"
International Conference on Molecular Science
2023年8月
Tsukuba International Congress Center, Ibaraki
"Novel Cyclic Compounds of Silicon and Germanium"
103rd CSJ Annual Meeting
2023年3月
Nihon University, Tokyo

招待講演 / Invited Lectures

"Recent Developments in Heavier Group 14 Multiple Bonds"
International Symposium on Main Group Chemistry
2023年12月
Online
Invited Lecture
"Novel Aspects of Silicon Chemistry"
Asian Silicon Chemistry Workshop
2022年9月
Seoul National University, Korea (Online)
Invited Lecture

For presentation materials and posters, please contact me if needed.

講義

有機化学（2026年度）シラバス 講義スライド：典型元素化学入門

マニュアル

安全衛生マニュアル NMR測定手順