主だったものを本ページで公開します。2017年以前の論文リストは、PDFファイルでご案内します(準備中)
Original Papers
| 94) | Miyazaki, D.; Eto, Reo; Ichikawa, J.; Fuchibe, K. "Gold(I)-Catalyzed [2 + 4] Cycloaddition of | ||
| 1,1-Difluoroallenes with Conjugated Enones: Synthesis of Ring-Difluorinated Dihydro-2H-Pyrans," | |||
| Chem. Commun., 2025, 61, (23), 4563–4566. | |||
| doi:10.1039/D4CC06642A. | |||
| 93) | Fuchibe, K.; Mitsumori, M.; Ishikawa, K.; Ichikawa, J. "Synthesis of Monofluoroalkene-Based | ||
| Dipeptide Bioisosteres via Regioselective Ring Opening of 1,1-Difluorocyclopropanes," | |||
| Synthesis 2025, 57 (08), 1506–1516. | |||
| doi:10.1055/a-2509-5342. | |||
| 92) | Miyazaki, D.; Kudo, K.; Fujiki, Y.; Watanabe, N.; Matsui, T.; Ichikawa, J.; Fuchibe, K. | ||
| "Gold(I)-Catalyzed [2 + 2] and [3 + 2] Cycloadditions of 1,1-Difluoroallenes with Aldehydes: | |||
| Switchable Syntheses of Fluorinated Oxetanes and Furans," Org. Lett. 2025, 27 (15) , 3807–3812. | |||
| doi:10.1021/acs.orglett.4c04185. [Cover Picture] https://pubs.acs.org/toc/orlef7/27/15. | |||
| 91) | Fujita, T.; Yabuki, H.; Morioka, R.; Fuchibe, K.; Ichikawa, J. "Nickel-Catalyzed Cross-Coupling of | ||
| 2-Fluorobenzofurans with Arylboronic Acids via Aromatic C–F Bond Activation," | |||
| Beilstein J. Org. Chem. 2025, 21 , 146–154. | |||
| doi:10.3762/bjoc.21.8 | |||
| 90) | Fuchibe, K.; Matsunobu, T.; Ichikawa, J. "Synthesis of Substituted (Trifluoromethyl)alkenes: | ||
| (Trifluoromethyl)alkylidenation of Thioketones via CF3-Thiiranes," J. Fluorine Chem. 2024, | |||
| 275, 110273. | |||
| doi:10.1016/j.jfluchem.2024.110273 Tsukuba repository (2026/3/22以降にアクセス可能) | |||
| 89) | Fuchibe, K.; Sakon, K.; Suto, K.; Eto, R.; Nakazono, S.; Ichikawa, J. | ||
| "Fluorine-Activated and -Directed Allene Cycloadditions with Nitrile/Imine Oxides: | |||
| Synthesis of Ring-Fluorinated Isoxazole Derivatives," Org. Lett. 2023, 25 (39), 7258–7262. | |||
| doi: 10.1021/acs.orglett.3c02879 Tsukuba repository | |||
| 88) | Fuchibe, K.; Matsuo, T.; Ichikawa, J. "Synthesis of 2-Difluoroethylated 2H-1,3-Benzoxazines via | ||
| Proton-Mediated Ring Opening/Interrupted Ritter Reaction of 1,1-Difluorocyclopropanes," | |||
| Org. Lett. 2023. 25 (23), 4276–4280. | |||
| doi: 10.1021/acs.orglett.3c01277 Tsukuba repository | |||
| 87) | Fuchibe, K.; Ichikawa, J. "Generation of Difluorocarbenes and Introduction of Fluorinated | ||
| One Carbon Units into Carbonyl and Related Compounds," Chem. Commun. 2023, 59 (18), | |||
| 2532–2540. | |||
| doi: 10.1039/D2CC03950H Tsukuba repository | |||
| 86) | Takao, G.; Hakozaki, T.; Miura, K.; Urushibara, Y.; Fuchibe, K.; Ichikawa, J. "Construction of Substituted [4]Acene | ||
| Frameworks Based on Double Cationic Cyclizations of Fluoroalkenes," Synthesis 2022, 54 (17), 3883–3898. | |||
| doi: 10.1055/s-0037-1610791 Tsukuba repository | |||
| 85) | Fuchibe, K.; Morota, Y.; Miura, T.; Ichikawa, J. "Difluorocarbene-Based [4 + 1] Cycloaddition Strategy for | ||
| Synthesizing Derivatives of 5-Fluorinated Thiazoles and Oxazoles," Chem. Lett. 2022, 51 (7), 778–780. | |||
| doi: 10.1246/cl.220212 Tsukuba repository | |||
| 84) | Fuchibe, K.; Mukohara, I.; Yamada, A.; Miyazaki, D.; Takayama, R.; Ichikawa, J. "Construction of Thienothiophene | ||
| and Thienofuran Ring Systems via Ring Expansion of Difluorothiiranes Generated from Dithioesters," Org. Lett. | |||
| 2022, 24 (1), 169–174. | |||
| doi: 10.1021/acs.orglett.1c03805 Tsukuba repository | |||
| 83) | Fuchibe, K.; Yamada, A.; Hachinohe, K.; Matsumoto, K.; Ichikawa, J. "Synthesis of Difluoroalkenes from Thiocarbonyl | ||
| Compounds via Difluorothiiranes: Electrophilic Counterpart to Wittig-Type Difluoromethylidenation," Bull. Chem. Soc. |
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| Jpn. 2021, 94 (10), 2451–2465. | |||
| doi: 10.1246/bcsj.20210248 Tsukuba repository | |||
| BCSJ Selected Paper, Inside Cover | |||
| 82) | Fuchibe, K.; Fushihara, T.; Ichikawa, J. "Synthesis of Ring-Fluorinated Thiophene Derivatives Based on Single C–F | ||
| Bond Activation of CF3-Cyclopropanes: Sulfanylation and 5-endo-trig Cyclization," Org. Lett. 2020, 22 (6), |
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| 2201–2205. | |||
| doi: 10.1021/acs.orglett.0c00385 Tsukuba repository | |||
| 81) | Fuchibe, K.; Abe, M.; Sasaki, M.; Ichikawa, J. "Gold-Catalyzed Electrophilic Activation of 1,1-Difluoroallenes: alpha- | ||
| and gamma-Selective Addition of Heteroatom Nucleophiles," J. Fluorine Chem. 2020, 232, 109452–109452. | |||
| doi: 10.1016/j.jfluchem.2020.109452 Tsukuba repository | |||
| 80) | Fuchibe, K.; Abe, M.; Idate, H.; Ichikawa, J. "Fluorinated Phenanthrenes as Aryne Precursors: PAH Synthesis Based | ||
| on Domino Ring Assembly Using 1,1-Difluoroallenes," Chem. Asian J. 2020, 15 (8), 1384–1392. | |||
| doi: 10.1002/asia.202000069 Tsukuba repository | |||
| 79) | Fuchibe, K.; Watanabe, S.; Takao, G.; Ichikawa, J. "Synthesis of (Difluoromethyl)naphthalenes Using the Ring | ||
| Construction Strategy: C–C Bond Formation on the Central Carbon of 1,1-Difluoroallenes via Pd-catalyzed insertion," | |||
| Org. Biomol. Chem. 2019, 17 (20), 5047–5054. | |||
| doi: 10.1039/C9OB00540D Tsukuba repository | |||
| 78) | Fuchibe, K.; Tsuda, N.; Ichikawa, J. "Construction of Pinpoint-Fluorinated Benzothiophene Frameworks Using | ||
| Palladium-Catalyzed Cyclization of o-(Fluorovinyl)phenyl-Substituted Thiophenes," Heterocycles 2019, 99 (2), | , | ||
| 1196–1216. | |||
| doi: 10.3987/COM-18-S(F)95 Tsukuba repository | |||
| 77) | Fuchibe, K.; Takao, G.; Takahashi, H.; Ijima, S.; Ichikawa, J. "Methylarene-Based PAH Synthesis via Domino Cyclization | ||
| of 1,1-Difluoro-1-alkenes," Bull. Chem. Soc. Jpn. 2019, 92 (12), 2019–2029. | , | ||
| doi: 10.1246/bcsj.20190252 Tsukuba repository | |||
| 76) | Takayama, R.; Fuchibe, K.; Ichikawa, J. "Metal-Free Synthesis of alpha,alpha-Difluorocyclopentanone Derivatives via | ||
| Regioselective Difluorocyclopropanation/VCP Rearrangement of Silyl Dienol Ethers," ARKIVOC 2018, ii, 72–80. | , | ||
| doi: 10.24820/ark.5550190.p010.290 Tsukuba repository | |||
| 75) | Fuchibe, K.; Oki, R.; Hatta, H.; Ichikawa, J. "Single C−F Bond Activation of the CF3 Group with a Lewis Acid: CF3- | ||
| Cyclopropanes as Versatile 4,4-Difluorohomoallylating Agents," Chem. Eur. J. 2018, 24 (68):17932–17935. | , | ||
| doi: 10.1002/chem.201805054 Tsukuba repository | |||
| Wiley Top Downloaded Paper2018–2019 |
Accounts
| 9) | 渕辺耕平; 市川淳士 "ジフルオロカルベンによる環フッ素化ヘテロ五員環の構築法," | ||
| in 有機フッ素化合物の合成と応用最前線 (ed.: 今野勉), ファインケミカルシリーズ, pp. 41–52 | |||
| シーエムシー出版. | |||
| ISBN: 978-4-7813-1858-5 | |||
| 8) | Fuchibe, K.; Fujita, T.; Ichikawa, J. "Synthetic Organic Reactions via alpha-Fluorocarbocations | ||
| α-フルオロカルボカチオンを中間体とする有機合成反応," in フッ素の特性が織りなす分子変換・材料化学 | |||
| フッ素化学の新たな飛躍に向けて (ed.: The Chemical Society of Japan), CSJ Current Review, Vol. 47, | |||
| pp. 91–97, Kagakudojin. | |||
| ISBN: 9784759814071 | |||
| 7) | Fuchibe, K.; Ichikawa, J. "Synthesis of Fluorine-Containing Heterocyclic Compounds via Direct and Indirect | ||
| Methods Using Difluorocarbenes," in Targents in Heterocyclic Systems – Chemistry and Properties | |||
| (eds.: Attanasi, O. A.; Gabriele, B.; Spinelli, D.), Vol. 2, pp. 443–460, The Italian Chemical Society. | |||
| doi: http://dx.medra.org/10.17374/targets.2024.27.443 | |||
| 6) | Fuchibe, K.; Fujita, T.; Ichikawa, J. "Pinpoint-Fluorinated Polycyclic Aromatic Hydrocarbons | ||
| (F-PAHs) and Their Heteroaromatic Analogs: Syntheses, Reactivities, and Properties," Bull. Chem. | |||
| Soc. Jpn. 2024, 97(3), uoad024. | |||
| doi: 10.1093/bulcsj/uoad024 | |||
| 5) | Fuchibe, K.; Ichikawa, J. "Generation of Free and Metal Difluorocarbenes and Introduction of | ||
| Fluorinated One Carbon Units into Carbonyl and Related Compounds," Chem. Commun. 2018, | |||
| 59 (18), 2532–2540. | |||
| doi: 10.1039/D2CC03950 Tsukuba repository | |||
| 4) | Fuchibe, K.; Takayama, R.; Aono, T.; Hu, J.; Hidano, T.; Sasagawa, H.; Fujiwara, M.; Miyazaki, S.; Nadano, R.; Ichikawa, J. | ||
| "Regioselective Syntheses of Fluorinated Cyclopentanone Derivatives: Ring Construction Strategy Using Transition- | |||
| Metal–Difluorocarbene Complexes and Free Difluorocarbene," Synthesis 2018, 50 (3), 514–528. | |||
| doi: 10.1055/s-0036-1591728 | |||
| 3) | Fuchibe, K.; Ichikawa, J. "Fluorine-Directed and -Activated Nazarov Cyclizations: Selective Synthesis of Fluorinated | ||
| Cyclopentenones," Chim. Oggi. 2018, 36 (3), 36–39. | |||
| visit web | |||
| 2) | Fuchibe, K.; Fujita, T.; Ichikawa, J. "Pinpoint-Fluorinated Polycyclic Aromatic Hydrocarbons (F–PAHs): Their Synthesis | ||
| via Electrophilic Activation of Fluoroalkenes and Properties ピンポイントフッ素化多環式芳香族炭化水素(F-PAH)： | |||
| フルオロアルケンの求電子的活性化による合成と性質," J. Synth. Org. Chem., Jpn. 2018, 76 (9), 938–953. | |||
| doi: 10.5059/yukigoseikyokaishi.76.938 | |||
| 1) | Fuchibe, K.; Akiyama, T. "Catalytic Activation of Carbon-fluorine Bonds by Low-valent Niobium Species 低原子価 | ||
| ニオブ種による炭素-フッ素結合の触媒的活性化反応," J. Synth. Org. Chem., Jpn. 2009, 67 (3), 208–218. | |||
| doi: 10.5059/yukigoseikyokaishi.67.208 |
Reviews
| 3) | Fuchibe, K.; Ichikawa, J. "Discussion Addendum for: Preparation of 1,1-Difluoroallenes by Difluorovinylidenation | ||
| of Carbonyl Compounds," Org. Synth. 2022, 99, 113–124. | |||
| doi: 10.15227/orgsyn.99.0113 Tsukuba Repository | |||
| 2) | Fuchibe, K.; Fujita, T.; Ichikawa, J. "C–F Bond Activation Reactions" in Comprehensive Organometallic Chemistry IV | ||
| (eds.: Parkin, G.; Meyer, K.; O’Hare, D., Elsevier, Amsterdam, 2022, Vol. 12, Ch. 12.11, pp. 421–464. | |||
| doi: 10.1016/B978-0-12-820206-7.00147-5 | |||
| 1) | Fujita, T.; Fuchibe, K.; Ichikawa, J. "Transition-Metal-Mediated and -Catalyzed C−F Bond Activation by Fluorine | ||
| Elimination," Angew. Chem. Int. Ed. 2019, 58 (2), 390–402. | |||
| doi: 10.1002/anie.201805292 |