渕辺グループ 論文リスト

主だったものを本ページで公開します。2017年以前の論文リストは、PDFファイルでご案内します(準備中)

Original Papers 

90) Fuchibe, K., Matsunobu, T.; Ichikawa, J. "Synthesis of Substituted (Trifluoromethyl)alkenes:
(Trifluoromethyl)alkylidenation of Thioketones via CF3-Thiiranes," J. Fluorine Chem. 2024,
275,  110273.
doi:10.1016/j.jfluchem.2024.110273Tsukuba repository (2026/3/22以降にアクセス可能)
89) Fuchibe, K.; Sakon, K.; Suto, K.; Eto, R.; Nakazono, S.; Ichikawa, J.
Fluorine-Activated and -Directed Allene Cycloadditions with Nitrile/Imine Oxides:
Synthesis of Ring-Fluorinated Isoxazole Derivatives," Org. Lett. 2023, 25 (39), 7258–7262.
doi: 10.1021/acs.orglett.3c02879Tsukuba repository (2024/9/25以降にアクセス可能)
88) Fuchibe, K.; Matsuo, T.; Ichikawa, J. "Synthesis of 2-Difluoroethylated 2H-1,3-Benzoxazines via
Proton-Mediated Ring Opening/Interrupted Ritter Reaction of 1,1-Difluorocyclopropanes,"
Org. Lett. 2023. 25 (23), 4276–4280.
doi: 10.1021/acs.orglett.3c01277Tsukuba repository
87) Fuchibe, K.;   Ichikawa, J. "Generation of Difluorocarbenes and Introduction of Fluorinated
One Carbon Units into Carbonyl and Related Compounds," Chem. Commun. 2023, 59 (18), 2532–2540.
doi: 10.1039/D2CC03950HTsukuba repository
86) Takao, G.; Hakozaki, T.; Miura, K.; Urushibara, Y.; Fuchibe, K.; Ichikawa, J. "Construction of Substituted [4]Acene
Frameworks Based on Double Cationic Cyclizations of Fluoroalkenes," Synthesis  2022, 54 (17), 3883–3898.
doi: 10.1055/s-0037-1610791Tsukuba repository
85) Fuchibe, K.; Morota, Y.; Miura, T.; Ichikawa, J. "Difluorocarbene-Based [4 + 1] Cycloaddition Strategy for
Synthesizing Derivatives of 5-Fluorinated Thiazoles and Oxazoles," Chem. Lett. 202251 (7), 778–780.  
doi: 10.1246/cl.220212Tsukuba repository
84) Fuchibe, K.; Mukohara, I.; Yamada, A.; Miyazaki, D.; Takayama, R.; Ichikawa, J. "Construction of Thienothiophene
and Thienofuran Ring Systems via Ring Expansion of Difluorothiiranes Generated from Dithioesters," Org. Lett.
  2022, 24 (1), 169–174. 
  doi: 10.1021/acs.orglett.1c03805Tsukuba repository
83) Fuchibe, K.; Yamada, A.; Hachinohe, K.; Matsumoto, K.; Ichikawa, J. "Synthesis of Difluoroalkenes from Thiocarbonyl  
Compounds via Difluorothiiranes: Electrophilic Counterpart to Wittig-Type Difluoromethylidenation," Bull. Chem. Soc.
  Jpn. 2021, 94 (10), 2451–2465.  
  doi: 10.1246/bcsj.20210248Tsukuba repository
  BCSJ Selected Paper, Inside Cover
82) Fuchibe, K.; Fushihara, T.; Ichikawa, J. "Synthesis of Ring-Fluorinated Thiophene Derivatives Based on Single C–F
Bond Activation of CF3-Cyclopropanes: Sulfanylation and 5-endo-trig Cyclization," Org. Lett. 2020, 22 (6),
  2201–2205.
  doi: 10.1021/acs.orglett.0c00385Tsukuba repository
81) Fuchibe, K.; Abe, M.; Sasaki, M.; Ichikawa, J. "Gold-Catalyzed Electrophilic Activation of 1,1-Difluoroallenes: alpha-
and gamma-Selective Addition of Heteroatom Nucleophiles," J. Fluorine Chem. 2020, 232, 109452–109452.
  doi: 10.1016/j.jfluchem.2020.109452Tsukuba repository
80) Fuchibe, K.; Abe, M.; Idate, H.; Ichikawa, J. "Fluorinated Phenanthrenes as Aryne Precursors: PAH Synthesis Based
on Domino Ring Assembly Using 1,1-Difluoroallenes," Chem. Asian J. 2020, 15 (8), 1384–1392. 
  doi: 10.1002/asia.202000069Tsukuba repository
79) Fuchibe, K.; Watanabe, S.; Takao, G.; Ichikawa, J. "Synthesis of (Difluoromethyl)naphthalenes Using the Ring
Construction Strategy: C–C Bond Formation on the Central Carbon of 1,1-Difluoroallenes via Pd-catalyzed insertion,"
Org. Biomol. Chem. 2019, 17 (20), 5047–5054.
  doi: 10.1039/C9OB00540DTsukuba repository
78) Fuchibe, K.; Tsuda, N.; Ichikawa, J. "Construction of Pinpoint-Fluorinated Benzothiophene Frameworks Using
Palladium-Catalyzed Cyclization of o-(Fluorovinyl)phenyl-Substituted Thiophenes," Heterocycles 2019, 99 (2),
1196–1216.
  doi: 10.3987/COM-18-S(F)95Tsukuba repository
77) Fuchibe, K.; Takao, G.; Takahashi, H.; Ijima, S.; Ichikawa, J. "Methylarene-Based PAH Synthesis via Domino Cyclization
of 1,1-Difluoro-1-alkenes," Bull. Chem. Soc. Jpn. 2019, 92 (12), 2019–2029.
  doi: 10.1246/bcsj.20190252Tsukuba repository
76) Takayama, R.; Fuchibe, K.; Ichikawa, J. "Metal-Free Synthesis of alpha,alpha-Difluorocyclopentanone Derivatives via
 Regioselective Difluorocyclopropanation/VCP Rearrangement of Silyl Dienol Ethers," ARKIVOC 2018, ii, 72–80.
  doi: 10.24820/ark.5550190.p010.290Tsukuba repository
75) Fuchibe, K.; Oki, R.; Hatta, H.; Ichikawa, J. "Single C−F Bond Activation of the CF3 Group with a Lewis Acid: CF3-
Cyclopropanes as Versatile 4,4-Difluorohomoallylating Agents," Chem. Eur. J. 2018, 24 (68):17932–17935.
  doi: 10.1002/chem.201805054Tsukuba repository
  Wiley Top Downloaded Paper2018–2019

Accounts

8) Fuchibe, K.; Fujita, T.; Ichikawa, J. "Synthetic Organic Reactions via alpha-Fluorocarbocations
  α-フルオロカルボカチオンを中間体とする有機合成反応," in フッ素の特性が織りなす分子変換・材料化学
  フッ素化学の新たな飛躍に向けて (ed.: The Chemical Society of Japan), CSJ Current Review, Vol. 47,
  pp. 91–97, Kagakudojin.
  ISBN: 9784759814071
7) Fuchibe, K.; Ichikawa, J. "Synthesis of Fluorine-Containing Heterocyclic Compounds via Direct and Indirect
Methods Using Difluorocarbenes," in Targents in Heterocyclic Systems – Chemistry and Properties
(eds.: Attanasi, O. A.; Gabriele, B.; Spinelli, D.), Vol. 2, pp. 443–460, The Italian Chemical Society. 
doi: http://dx.medra.org/10.17374/targets.2024.27.443
6) Fuchibe, K.; Fujita, T.; Ichikawa, J. "Pinpoint-Fluorinated Polycyclic Aromatic Hydrocarbons (F-PAHs) and
Their Heteroaromatic Analogs: Syntheses, Reactivities, and Properties," Bull. Chem. Soc. Jpn. in press.
doi: 10.1093/bulcsj/uoad024
5) Fuchibe, K.; Ichikawa, J. "Generation of Free and Metal Difluorocarbenes and Introduction of Fluorinated One Carbon
Units into Carbonyl and Related Compounds," Chem. Commun. 2018, 59 (18), 2532–2540.
doi: 10.1039/D2CC03950   Tsukuba repository
4) Fuchibe, K.; Takayama, R.; Aono, T.; Hu, J.; Hidano, T.; Sasagawa, H.; Fujiwara, M.; Miyazaki, S.; Nadano, R.; Ichikawa, J.
"Regioselective Syntheses of Fluorinated Cyclopentanone Derivatives: Ring Construction Strategy Using Transition-
Metal–Difluorocarbene Complexes and Free Difluorocarbene," Synthesis 2018, 50 (3), 514–528.
  doi: 10.1055/s-0036-1591728
3) Fuchibe, K.; Ichikawa, J. "Fluorine-Directed and -Activated Nazarov Cyclizations: Selective Synthesis of Fluorinated
Cyclopentenones," Chim. Oggi. 2018, 36 (3), 36–39.
  visit web 
2) Fuchibe, K.; Fujita, T.; Ichikawa, J. "Pinpoint-Fluorinated Polycyclic Aromatic Hydrocarbons (F–PAHs): Their Synthesis
via Electrophilic Activation of Fluoroalkenes and Properties ピンポイントフッ素化多環式芳香族炭化水素(F-PAH):
フルオロアルケンの求電子的活性化による合成と性質," J. Synth. Org. Chem., Jpn. 2018, 76 (9), 938–953.  
  doi: 10.5059/yukigoseikyokaishi.76.938
1) Fuchibe, K.; Akiyama, T. "Catalytic Activation of Carbon-fluorine Bonds by Low-valent Niobium Species 低原子価
ニオブ種による炭素-フッ素結合の触媒的活性化反応," J. Synth. Org. Chem., Jpn. 2009, 67 (3), 208–218.
  doi: 10.5059/yukigoseikyokaishi.67.208

Reviews

3) Fuchibe, K.; Ichikawa, J. "Discussion Addendum for: Preparation of 1,1-Difluoroallenes by Difluorovinylidenation  
of Carbonyl Compounds," Org. Synth. 2022, 99, 113–124.      
doi: 10.15227/orgsyn.99.0113Tsukuba Repository
2) Fuchibe, K.; Fujita, T.; Ichikawa, J. "C–F Bond Activation Reactions" in Comprehensive Organometallic Chemistry IV  
(eds.: Parkin, G.; Meyer, K.; O’Hare, D., Elsevier, Amsterdam, 2022, Vol. 12, Ch. 12.11, pp. 421–464.      
  doi: 10.1016/B978-0-12-820206-7.00147-5
1) Fujita, T.; Fuchibe, K.; Ichikawa, J. "Transition-Metal-Mediated and -Catalyzed C−F Bond Activation by Fluorine
Elimination," Angew. Chem. Int. Ed. 2019, 58 (2), 390–402.  
  doi: 10.1002/anie.201805292