- S. Enami,* N. Numadate, T. Hama
Atmospheric Intermediates at the Air-Water Interface
J. Phys. Chem. A (Featured Article) 2024, 128, 5419-5434. JPCA Most Read Articles Atmospheric Intermediates at the Air–Water Interface | The Journal of Physical Chemistry A (acs.org) - S. Saito, N. Numadate, H. Teraoka, S. Enami, H. Kobayashi, T. Hama
Impurity contribution to ultraviolet absorption of saturated fatty acids
Sci. Adv., 2023, 9, eadj6438. Impurity contribution to ultraviolet absorption of saturated fatty acids (science.org) プレスリリース p20230921030000.pdf (tsukuba.ac.jp) - S. Enami*, Y. Morino, K. Sato
Mechanism of Fenton oxidation of levoglucosan in water
J. Phys. Chem. A., 2023, 127, 2975-2985. “Michael R. Hoffmann Festschrift”
https://pubs.acs.org/doi/10.1021/acs.jpca.3c00512 - J. Qiu, M. Fujita, K. Tonokura, S. Enami*
Stability of terpenoid-derived secondary ozonides in aqueous organic media
J. Phys. Chem. A., 2022, 126, 5386-5397. Special issue “Advances in Atmospheric Chemical and Physical Processes”
https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.2c04077 - S. Enami*
Proton-catalyzed decomposition of multifunctionalized organic hydroperoxides derived from the reactions of Criegee intermediates with ethylene glycol in aqueous organic media
ACS Earth Space Chem., 2022, 6, 1937-1947.
https://pubs.acs.org/doi/10.1021/acsearthspacechem.2c00142 - Y. Endo, Y. Sakamoto, Y. Kajii, S. Enami*
Decomposition of multifunctionalized alpha-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with diols in liquid phases
Phys. Chem. Chem. Phys., 2022, 24, 11562-11572. PCCP HOT Articles
https://pubs.rsc.org/en/content/articlelanding/2022/cp/d2cp00915c - M. Hu, K. Chen, J. Qiu, Y. H. Lin, K. Tonokura, S. Enami*
Decomposition mechanism of alpha-alkoxyalkyl-hydroperoxides in the liquid phase: Temperature dependent kinetics and theoretical calculations
Environ. Sci.: Atmos., 2022, 2, 241-251.
https://pubs.rsc.org/en/content/articlepdf/2022/ea/d1ea00076d - M. Hu, K. Tonokura, Y. Morino, K. Sato, S. Enami*
Effects of metal ions on aqueous-phase decomposition of α-hydroxyalkyl-hydroperoxides derived from terpene alcohols
Environ. Sci. Technol., 2021, 55, 12893-12901.
https://pubs.acs.org/doi/pdf/10.1021/acs.est.1c04635 - S. Enami*
Fates of organic hydroperoxides in atmospheric condensed phases
J. Phys. Chem. A., 2021, 125, 4513-4523. JPCA Most Read Articles
https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.1c01513 - M. Hu, J. Qiu, K. Tonokura, S. Enami*
Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reaction of Criegee intermediates with alcohols
Phys. Chem. Chem. Phys., 2021, 23, 4605-4614. PCCP HOT Articles
https://pubs.rsc.org/en/content/articlelanding/2021/cp/d0cp06308h - M. Hu, K. Chen, J. Qiu, Y. H. Lin, K. Tonokura, S. Enami*
Temperature dependence of aqueous-phase decomposition of alpha-hydroxyalkyl-hydroperoxides
J. Phys. Chem. A., 2020, 124, 10288-10295.
https://pubs.acs.org/doi/10.1021/acs.jpca.0c09862 - J. Qiu, K. Tonokura, S. Enami*
Proton-catalyzed decomposition of α-hydroxyalkyl-hydroperoxides in water
Environ. Sci. Technol., 2020, 54, 10561-10569. ES&T Most Read Articles
https://pubs.acs.org/doi/pdf/10.1021/acs.est.0c03438 - J. Qiu, Z. Liang, K. Tonokura, A. J. Colussi*, S. Enami*
Stability of monoterpene-derived α-hydroxyalkyl-hydroperoxides in aqueous organic media: Relevance to the fate of hydroperoxides in aerosol particle phases
Environ. Sci. Technol., 2020, 54, 3890-3899.
https://pubs.acs.org/doi/10.1021/acs.est.9b07497 - S. Ishizuka, A. Matsugi, T. Hama, S. Enami*
Interfacial water mediates oligomerization pathways of monoterpene carbocations
J. Phys. Chem. Lett., 2020, 11, 67-74.
https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.9b03110 - J. Qiu, S. Ishizuka, K. Tonokura, A. J. Colussi, S. Enami*
Water dramatically accelerates the decomposition of α-hydroxyalkyl-hydroperoxides in aerosol particles
J. Phys. Chem. Lett., 2019, 10, 5748-5755. JPCL Most Read Articles
https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.9b01953 - S. Ishizuka, T. Hama, S. Enami*
Acid-catalyzed oligomerization at the air–water interface modified by competitive adsorption of surfactants
J. Phys. Chem. C, 2019, 123, 21662-21669.
https://pubs.acs.org/doi/10.1021/acs.jpcc.9b07380 - J. Qiu, S. Ishizuka, K. Tonokura, K. Sato, S. Inomata, S. Enami*
Effects of pH on interfacial ozonolysis of alpha-terpineol
J. Phys. Chem. A, 2019, 123, 7148-7155.
https://pubs.acs.org/doi/10.1021/acs.jpca.9b05434 - J. Qiu, S. Ishizuka, K. Tonokura, S. Enami*
Interfacial vs bulk ozonolysis of nerolidol
Environ. Sci. Technol., 2019, 53, 5750-5757. ES&T Most Read Articles
https://pubs.acs.org/doi/pdf/10.1021/acs.est.9b00364 - S. Enami*, S. Ishizuka, A. J. Colussi*
Chemical signatures of surface microheterogeneity on liquid mixtures
J. Chem. Phys., 2019, 150, 024702 (8 pages).
https://pubs.aip.org/aip/jcp/article/150/2/024702/197391/Chemical-signatures-of-surface-microheterogeneity - S. Ishizuka, A. Matsugi, T. Hama, S. Enami*
Chain-propagation, chain-transfer, and hydride-abstraction by cyclic carbocations on water surfaces
Phys. Chem. Chem. Phys., 2018, 20, 25256-25267. PCCP HOT Articles
https://pubs.rsc.org/en/content/articlelanding/2018/cp/c8cp04993a - J. Qiu, S. Ishizuka, K. Tonokura, A. J. Colussi, S. Enami*
Reactivity of monoterpene Criegee intermediates at gas-liquid interfaces
J. Phys. Chem. A, 2018, 122, 7910-7917. JPCA Most Read Articles
https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.8b06914 - J. Qiu, S. Ishizuka, K. Tonokura, S. Enami*
Reactions of Criegee intermediates with benzoic acid at the gas/liquid interface
J. Phys. Chem. A, 2018, 122, 6303–6310.
https://pubs.acs.org/doi/10.1021/acs.jpca.8b04995 - S. Ishizuka, T. Fujii, A. Matsugi, Y. Sakamoto*, T. Hama*, S. Enami*
Controlling factors of oligomerization at the water surface: Why is isoprene such a unique VOC?
Phys. Chem. Chem. Phys., 2018, 20, 15400-15410.
https://pubs.rsc.org/en/content/articlelanding/2018/cp/c8cp01551a - S. Enami*, M. R. Hoffmann, A. J. Colussi
Criegee intermediates react with levoglucosan on water
J. Phys. Chem. Lett., 2017, 8, 3888-3894.
https://pubs.acs.org/doi/10.1021/acs.jpclett.7b01665 - S. Enami*, A. J. Colussi*
Reactions of Criegee intermediates with alcohols at air-aqueous interfaces
J. Phys. Chem. A, 2017, 121, 5175-5182.
https://pubs.acs.org/doi/10.1021/acs.jpca.7b04272 - S. Enami*, A. J. Colussi*
Efficient scavenging of Criegee intermediates on water by surface-active cis-pinonic acid
Phys. Chem. Chem. Phys., 2017, 19, 17044-17051. PCCP HOT Articles
https://pubs.rsc.org/en/content/articlelanding/2017/cp/c7cp03869k - S. Enami*, A. J. Colussi*
Criegee chemistry on aqueous organic surfaces
J. Phys. Chem. Lett., 2017, 8, 1615-1623. JPCL Most Read Articles
https://pubs.acs.org/doi/10.1021/acs.jpclett.7b00434 - K. Matsuoka, Y. Sakamoto, T. Hama, Y. Kajii, S. Enami*
Reactive uptake of gaseous sesquiterpenes on aqueous surfaces
J. Phys. Chem. A, 2017, 121, 810-818.
https://pubs.acs.org/doi/10.1021/acs.jpca.6b11821 - S. Enami*, M. R. Hoffmann, A. J. Colussi*
Extensive H-atom abstraction from benzoate by OH-radicals at the air-water interface
Phys. Chem. Chem. Phys., 2016, 18, 31505-31512.
https://pubs.rsc.org/en/content/articlelanding/2016/cp/c6cp06652f - S. Enami*, T. Fujii, Y. Sakamoto, T. Hama, Y. Kajii
Carboxylate ion availability at the air-water interface
J. Phys. Chem. A, 2016, 120, 9224–9234.
https://pubs.acs.org/doi/10.1021/acs.jpca.6b08868 - S. Enami*, M. R. Hoffmann, A. J. Colussi
Halogen radical chemistry at aqueous interfaces
J. Phys. Chem. A, 2016, 120, 6242–6248.
https://pubs.acs.org/doi/10.1021/acs.jpca.6b04219 - S. Enami*, Y. Sakamoto
OH-radical oxidation of surface-active cis-pinonic acid at the air-water interface
J. Phys. Chem. A, 2016, 120, 3578−3587.
https://pubs.acs.org/doi/10.1021/acs.jpca.6b01261 - S. Enami*, Y. Sakamoto, K. Hara, K. Osada, M. R. Hoffmann, A. J. Colussi*
“Sizing” heterogeneous chemistry in the conversion of gaseous dimethyl sulfide to atmospheric particulates
Environ. Sci. Technol., 2016, 50, 1834–1843.
https://pubs.acs.org/doi/pdf/10.1021/acs.est.5b05337 - S. Enami*, M. R. Hoffmann, A. J. Colussi*
OH-radical specific addition to glutathione S-atom at the air-water interface – Relevance to the redox balance of the lung epithelial lining fluid
J. Phys. Chem. Lett., 2015, 6, 3935–3943.
https://pubs.acs.org/doi/pdf/10.1021/acs.jpclett.5b01819 - S. Enami*, M. R. Hoffmann, A. J. Colussi*
Stepwise oxidation of aqueous dicarboxylic acids by gas-phase OH-radicals
J. Phys. Chem. Lett., 2015, 6, 527–534.
https://pubs.acs.org/doi/10.1021/jz502432j - S. Enami*, A. J. Colussi*
Ion-specific long-range correlations on interfacial water driven by hydrogen bond fluctuations
J. Phys. Chem. B, 2014, 118, 1861-1866.
https://pubs.acs.org/doi/10.1021/jp411385u - S. Enami*, M. R. Hoffmann, A. J. Colussi
In situ mass spectrometric detection of interfacial intermediates in the oxidation of RCOOH(aq) by gas-phase OH-radicals
J. Phys. Chem. A, 2014, 118, 4130−4137.
https://pubs.acs.org/doi/10.1021/jp503387e - S. Enami*, Y. Sakamoto, A. J. Colussi*
Fenton chemistry at aqueous interfaces
Proc. Natl. Acad. Sci. U.S.A., 2014, 111, 623-628.
Highly cited paper (Top 1 %, Web of Science)
https://www.pnas.org/doi/epdf/10.1073/pnas.1314885111 - S. Enami*, A. J. Colussi*
Long-range Hofmeister effects of anionic and cationic amphiphiles
J. Phys. Chem. B, 2013, 117, 6276−6281.
https://pubs.acs.org/doi/10.1021/jp401285f - S. Enami*, A. J. Colussi*
Long-range specific ion-ion interactions in hydrogen-bonded liquid films
J. Chem. Phys., 2013, 138, 184706 (6 pages).
https://pubs.aip.org/aip/jcp/article/138/18/184706/985749/Long-range-specific-ion-ion-interactions-in - S. Enami*, M. R. Hoffmann, A. J. Colussi*
Dry deposition of biogenic terpenes via cationic oligomerization on environmental aqueous surfaces
J. Phys. Chem. Lett., 2012, 3, 3102–3108.
https://pubs.acs.org/doi/10.1021/jz301294q - H. Mishra, S. Enami, R. Nielsen, L. A. Stewart, M. R. Hoffmann, W. A. Goddard, A. J. Colussi
Brønsted basicity of the air-water interface
Proc. Natl. Acad. Sci. U.S.A., 2012, 109, 18679-18683.
https://www.pnas.org/doi/abs/10.1073/pnas.1209307109 - H. Mishra, S. Enami (equally contributed), R. Nielsen, M. R. Hoffmann, W. A. Goddard, A. J. Colussi
Anions dramatically enhance proton transfer through aqueous interfaces
Proc. Natl. Acad. Sci. U.S.A., 2012, 109, 10228-10232.
https://www.pnas.org/doi/10.1073/pnas.1200949109 - S. Enami*, H. Mishra, M. R. Hoffmann, A. J. Colussi*
Hofmeister effects in micromolar electrolyte solutions
J. Chem. Phys., 2012, 136, 154707 (5 pages).
https://pubs.aip.org/aip/jcp/article/136/15/154707/941640/Hofmeister-effects-in-micromolar-electrolyte - S. Enami, H. Mishra, M. R. Hoffmann, A. J. Colussi
Protonation and oligomerization of gaseous isoprene on mildly acidic surfaces – Implications for atmospheric chemistry
J. Phys. Chem. A, 2012, 116, 6027-6032. "A. R. Ravishankara Festschrift"
https://pubs.acs.org/doi/10.1021/jp2110133 - S. Enami, L. A. Stewart, M. R. Hoffmann, A. J. Colussi
Superacid chemistry on mildly acidic water
J. Phys. Chem. Lett., 2010, 1, 3488-3493.
https://pubs.acs.org/doi/10.1021/jz101402y - S. Enami, M. R. Hoffmann, A. J. Colussi
Prompt formation of organic acids in pulse ozonation of terpenes on aqueous surfaces
J. Phys. Chem. Lett., 2010, 1, 2374-2379.
https://pubs.acs.org/doi/10.1021/jz100847a - S. Enami, M. R. Hoffmann, A. J. Colussi
Molecular control of reactive gas uptake "on water"
J. Phys. Chem. A, 2010, 114, 5817-5822..
https://pubs.acs.org/doi/10.1021/jp1019729 - S. Enami, M. R. Hoffmann, A. J. Colussi
Proton availability at the air/water interface
J. Phys. Chem. Lett. 2010, 1, 1599-1604.
https://pubs.acs.org/doi/10.1021/jz100322w - S. Enami, M. R. Hoffmann, A. J. Colussi
Simultaneous detection of cysteine sulfenate, sulfinate and sulfonate during cysteine interfacial ozonolysis
J. Phys. Chem. B, 2009, 113, 9356-9358.
https://pubs.acs.org/doi/10.1021/jp904316n - S. Enami, M. R. Hoffmann, A. J. Colussi
How phenol and alpha-tocopherol react with ambient ozone at gas/liquid interfaces
J. Phys. Chem. A, 2009, 113, 7002-7010.
https://pubs.acs.org/doi/10.1021/jp901712k - S. Enami, M. R. Hoffmann, A. J. Colussi
Absorption of inhaled NO2
J. Phys. Chem. B, 2009, 113, 7977-7981.
https://pubs.acs.org/doi/10.1021/jp902667x - S. Enami, M. R. Hoffmann, A. J. Colussi
Ozone oxidizes glutathione to a sulfonic acid
Chem. Res. Toxicol., 2009, 22, 35-40.
https://pubs.acs.org/doi/10.1021/tx800298j - S. Enami, M. R. Hoffmann, A. J. Colussi
Acidity enhances the formation of a persistent ozonide at aqueous ascorbate/ozone gas interfaces
Proc. Natl. Acad. Sci. U.S.A., 2008, 105, 7365-7369.
https://www.pnas.org/doi/epdf/10.1073/pnas.0710791105 - S. Enami, C. D. Vecitis, J. Cheng, M. R. Hoffmann, A. J. Colussi
Global inorganic source of atmospheric bromine
J. Phys. Chem. A, 2007, 111, 8749-8752.
https://pubs.acs.org/doi/10.1021/jp074903r
